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- Article name
- FUNDAMENTAL EQUATION OF STATE FOR BROMOBENZENE
- Authors
- Grigoriev B. A. , , gba_41@mail.ru, Institute of Problems of Oil and Gasof the Russian Academy of Sciences, Moscow, Russia
Gerasimov A. A., , aager_kstu@mail.ru, Kaliningrad State Technical University, Kaliningrad, Russia
Alexandrov I. S., , alexandrov_kgrd@mail.ru, Kaliningrad State Technical University, Kaliningrad, Russia
- Keywords
- density / temperature / heat capacity / speed of sound / equation of state
- Year
- 2018 Issue 3 Pages 57 - 64
- Code EDN
- Code DOI
- Abstract
- An equation of state has been developed to represent the thermodynamic properties of bromobenzene. The equation allows the calculation of all thermodynamic properties and phase equilibrium over a temperature range from the triple point to 700 K with pressures up to 100 MPa. The uncertainties of properties: 0.15-0.3 % in density; 0.5-1.2 % in heat capacity; 0.2-0.5 % in the speed of sound; 0.5-1.0 % in vapor pressure and 0.05-0.1 % in saturated liquid density. To increase the stability of the equation, the data of molecular simulation obtained in this work were used for fitting.
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